Molecular structure and electrochemistry of carbon-bridged diferrocenyl compounds

Autor:	Hai-Long Hong, Rui-Jun Xie, Mei-Hua Luo, Quan-Ling Suo, Li-Min Han
Rok vydání:	2010
Předmět:	chemistry.chemical_compound Crystallography Chemistry Elemental analysis Stereochemistry Materials Chemistry Substituent Molecule Physical and Theoretical Chemistry Cyclic voltammetry Electrochemistry Single Crystal Diffraction
Zdroj:	Journal of Coordination Chemistry. 63:1700-1710
ISSN:	1029-0389 0095-8972
DOI:	10.1080/00958972.2010.487102
Popis:	Four diferrocenyl compounds: FcC(CH3)2Fc (1), Fc(CH3)C(C2H5)Fc (2), Fc(CH3)C(C3H7)Fc (3), and Fc(CH3)C(C6H5)Fc (4) were synthesized and characterized by NMR, FT-IR, MS, and elemental analysis. The molecular structures were determined by using X-ray single crystal diffraction. The electrochemical interactions between two ferrocenyl units in these compounds were investigated by cyclic voltammetry and theoretical calculation. The electron density of bridging carbon was a key factor for the separation of two ferrocenyl units.
Databáze:	OpenAIRE
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