Asymmetric synthesis of ?-methylaminoacids by the alkylation of glycine, alanine, and phenylalanine in chiral Ni(II) complexes
Autor: | N. S. Garbalinskaya, N. I. Chernoglazova, Yu. N. Belokon, Vladimir I. Bakhmutov, V. M. Belikov |
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Rok vydání: | 1987 |
Předmět: | |
Zdroj: | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 36:2595-2601 |
ISSN: | 1573-9171 0568-5230 |
DOI: | 10.1007/bf00957242 |
Popis: | Alkylation of alanine, phenylalanine, and glycine in the Ni(II) complexes of their Schiffs bases with S-2-N-(N′-benzylpropyl)aminobenzophenone followed by Chromatographic separation of the diastereomers has given optically pure S- and R-α-methyl-α-aminoacids. |
Databáze: | OpenAIRE |
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