Asymmetric synthesis of ?-methylaminoacids by the alkylation of glycine, alanine, and phenylalanine in chiral Ni(II) complexes

Autor: N. S. Garbalinskaya, N. I. Chernoglazova, Yu. N. Belokon, Vladimir I. Bakhmutov, V. M. Belikov
Rok vydání: 1987
Předmět:
Zdroj: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 36:2595-2601
ISSN: 1573-9171
0568-5230
DOI: 10.1007/bf00957242
Popis: Alkylation of alanine, phenylalanine, and glycine in the Ni(II) complexes of their Schiffs bases with S-2-N-(N′-benzylpropyl)aminobenzophenone followed by Chromatographic separation of the diastereomers has given optically pure S- and R-α-methyl-α-aminoacids.
Databáze: OpenAIRE