Zinc adsorption by lime‐treated montmorillonite clay

Autor: Tsau-don Tsai, P. Aarne Vesilind
Rok vydání: 1999
Předmět:
Zdroj: Journal of Environmental Science and Health, Part A. 34:103-124
ISSN: 1532-4117
1093-4529
Popis: In this research, lime‐treated montmorillonite clay is used to adsorb Zn(II) in a wide range of Zn(II) concentrations. Batch test results show that the adsorption of Zn(II) by montmorillonite appears to be dominated by different adsorption mechanisms. At low Zn(II) concentrations, chemisorption affects the amount of Zn(II) adsorbed by montmorillonite. When lime is added, physisorption becomes increasingly important. At high Zn(II) concentrations, physisorption is the dominant mechanism for Zn(II) adsorption. Lime also enhances the ability of montmorillonite to adsorb Zn(II) at low initial Zn(II) concentrations, and does not significantly affect the ability of montmorillonite to adsorb Zn(II) at high initial Zn(II) concentrations. In chemisorption, montmorillonite provides cation exchange sites for the adsorption of Zn(II). In physisorption, montmorillonite acts as not only nucleation center to adsorb zinc hydroxide‐oxides but also helps to coagulate the zinc hydroxide‐oxides. Lime‐treated clay ca...
Databáze: OpenAIRE