Efficient β-alkylation of secondary alcohols to α-substituted ketones catalyzed by functionalized Ir complexes via borrowing hydrogen in water
| Autor: | Xin Liu, Wen-Zhe Dong, Yang Li, Xiaoqiang Yu, Wan-Hui Wang, Yuichiro Himeda, Ming Bao |
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| Rok vydání: | 2023 |
| Předmět: | |
| Zdroj: | Organic Chemistry Frontiers. 10:355-362 |
| ISSN: | 2052-4129 |
| DOI: | 10.1039/d2qo01541b |
| Popis: | Highly efficient and selective alkylation via borrowing hydrogen in water was achieved with a functional Ir complex bearing an amidate ligand. The significant cooperation effect of the ligand on the high efficiency and selectivity was demonstrated. |
| Databáze: | OpenAIRE |
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