Ferromagnetic interactions in a dicyanamide-bridged multinuclear metal-organic framework [Pr3NH]+ [Mn(dca)3]−·H2O

Autor: Jie Yang, Yi-chun Ai, Zhen Rong, Xiu-feng Yu, Kun Qian, Yuan Huang
Rok vydání: 2019
Předmět:
Zdroj: Zeitschrift für Naturforschung B. 74:485-489
ISSN: 1865-7117
0932-0776
DOI: 10.1515/znb-2019-0015
Popis: A new complex [Pr3NH]+ [Mn(dca)3]− · H2O (dicyanamide = dca−) was synthesized, in which the Mn2+ cations are bridged by end-to-end dca anions to form three-dimensional [Mn(dca)3] n n − networks and tripropylammonium cations reside in the cavities of these networks. The complex has been characterized by single-crystal X-ray diffraction, infrared spectroscopy, elemental analysis, and magnetic measurements. Magnetic susceptibility data indicate ferromagnetic interactions among the MnII ions.
Databáze: OpenAIRE
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