ChemInform Abstract: A Simple Heterogeneous Catalyst for Phosphite Addition on Carbonyl Groups

Autor:	Veronica Santacroce, Raimondo Maggi, Emanuele Paris, Giovanni Maestri, Daniele Cauzzi
Rok vydání:	2016
Předmět:	Solvent Addition reaction Hydrotalcite Chemistry Reagent Condensation Organic chemistry General Medicine Heterogeneous catalysis Stoichiometry Catalysis
Zdroj:	ChemInform. 47
ISSN:	0931-7597
DOI:	10.1002/chin.201623204
Popis:	A cheap and easily recoverable heterogeneous catalyst could efficiently trigger C–P bond formation by selective addition of phosphites to the carbonyl group of aldehydes and ketones. The reactions afford the desired products in good to excellent yields and do not require the presence of a solvent. Furthermore, nearly stoichiometric amounts of reagents could be used as the hydrotalcite catalyst does not cause the condensation of the carbonyl derivatives, even when aliphatic aldehydes are employed.
Databáze:	OpenAIRE
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