Photochemical interaction of phosphine hydride complexes of molybdenum and tungsten with benzene and cyclohexane

Autor:	Yu. V. Gak, L. M. Ioffe, A. P. Pivovarov, Yu. G. Borod'ko
Rok vydání:	1984
Předmět:	chemistry.chemical_compound Denticity Cyclohexane Chemistry Hydride Molybdenum chemistry.chemical_element Dehydrogenation General Chemistry Tungsten Photochemistry Benzene Phosphine
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 33:700-702
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00947817
Popis:	1. Upon irradiation of phosphine hydride complexes of molybdenum and tungsten in benzene or cyclohexane, the products from photochemical dehydrogenation of the complexes are capable of abstracting hydrogen from the solvents, the molybdenum compounds being more reactive than the analogous tungsten complexes. 2. A decrease in the irradiation wavelength increases the efficiency of interaction of MH4L4 with the solvents. 3. Complexes with monodentate ligands are more reactive than complexes containing bidentate ligands.
Databáze:	OpenAIRE
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