Reaction of [Pt(NH3)4]Cl2·H2O with (NH4)6Mo7O24·4H2O in an aqueous alkaline solution at 190°C (autoclaving conditions)
| Autor: | E. V. Fesik, T. M. Buslayeva, T. I. Mel’nikova |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Aqueous solution
Ammonium heptamolybdate Inorganic chemistry Thermal decomposition chemistry.chemical_element 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Chloride 0104 chemical sciences Ammonia chemistry.chemical_compound chemistry medicine Titration Ammonium 0210 nano-technology Platinum medicine.drug |
| Zdroj: | Russian Journal of General Chemistry. 87:159-162 |
| ISSN: | 1608-3350 1070-3632 |
| DOI: | 10.1134/s1070363217020013 |
| Popis: | A solid product formed during thermolysis of tetraammineplatinum(II) chloride and ammonium heptamolybdate in an aqueous alkaline solution under autoclaving conditions has been studied by means of dynamic light scattering, scanning electron microscopy, X-ray diffraction analysis, and elemental analysis. The amount of free ammonia formed in the reaction has been determined by titration. The pathway of platinum(II) and heptamolybdate ions reduction by inner-sphere ammonium into the corresponding metals has been proposed. |
| Databáze: | OpenAIRE |
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