Five-Coordination and Adduct Formation in CoIII−Corrinoids Dissecting Ligand Substitution into Its Component Steps

Autor:	Eric A. Betterton, Rudi van Eldik, John M. Pratt, Pascal L. S. Harper, Mohamed S. A. Hamza
Rok vydání:	2002
Předmět:	Inorganic Chemistry Reaction mechanism chemistry.chemical_compound chemistry Ligand Stereochemistry Kinetics Molecule chemistry.chemical_element Corrinoids Cobalt Cobalamin Adduct
Zdroj:	European Journal of Inorganic Chemistry. 2002:580-583
ISSN:	1099-0682 1434-1948
DOI:	10.1002/1099-0682(200203)2002:3<580::aid-ejic580>3.0.co;2-z
Popis:	The equilibria between the five- and six-coordinate species of alkylcobinamide and cobalamin (base-off) have been studied using high-pressure spectroscopic techniques. The addition of a water molecule to the five-coordinate complex is accompanied by a volume decrease of 12 cm3·mol−1.
Databáze:	OpenAIRE
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