High Spin Molecules: [Mn12O12(O2CCH2Cl)16(H2O)4] and the One-electron Reduction Product [PPh4][Mn12O12(O2CCH2Cl)16(H2O)3]

Autor:	Gene-Hsiang Lee, Yu Wang, Hui Lien Tsai, Tyn Yih Jwo
Rok vydání:	2000
Předmět:	Crystallography Nuclear magnetic resonance Chemistry Product (mathematics) One-electron reduction Molecule General Chemistry Crystal structure Spin (physics) Magnetic susceptibility
Zdroj:	Chemistry Letters. 29:346-347
ISSN:	1348-0715 0366-7022
Popis:	The complex of [Mn12O12(O2CCH2Cl)16(H2O)4] was reduced by PPh4I to give a reduced complex [PPh4][Mn12O12(O2CCH2Cl)16(H2O)3]. Crystal structures of both complexes were determined by the X-ray method. The dc magnetic susceptibility measurements indicate that the neutral and reduced complexes are high spin species.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::280a8d34e9b234eef015b05321c96875 https://doi.org/10.1246/cl.2000.346 Zobrazit plný text záznamu