Bispentamethylcyclopentadienyl uranium(IV) thiolate compounds. Synthesis and reactions with CO2 and CS2

Autor:	Monique Lance, Martine Nierlich, Christophe Lescop, Thérèse Arliguie, Michel Ephritikhine
Rok vydání:	1999
Předmět:	Carbon disulfide Stereochemistry Chemistry Organic Chemistry Thermal decomposition chemistry.chemical_element Crystal structure Uranium Biochemistry Medicinal chemistry Inorganic Chemistry Elimination reaction chemistry.chemical_compound Materials Chemistry Physical and Theoretical Chemistry
Zdroj:	Journal of Organometallic Chemistry. 580:137-144
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(98)01139-5
Popis:	The bisthiolate uranium complexes [U(Cp*)2(SR)2] (R=Me, iPr, tBu, Ph) were synthesized by treatment of [U(Cp*)2(Cl)2] with NaSR; the crystal structure of [U(Cp*)2(SMe)2] was determined. Their reactions with CO2 or CS2 gave the insertion derivatives [U(Cp*)2(SR)(E2CSR)] (E=O and R=tBu; E=S and R=Me, iPr or tBu) and [U(Cp*)2(E2CSR)2] (E=O and R=tBu; E=S and R=Me or tBu); [U(Cp*)2(StBu)(S2CStBu)] was characterized by its crystal structure. Treatment of this latter with CO2 gave the mixed insertion complex [U(Cp*)2(O2CStBu)(S2CStBu)]. Thermolysis of the insertion compounds led to the reverse elimination reaction of CO2 and CS2. Reduction of [U(Cp*)2(O2CStBu)2] with Na(Hg) afforded the corresponding U(III) anionic complex.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::28061c56343e9cc1452e901ee7efcd78 https://doi.org/10.1016/s0022-328x(98)01139-5 Zobrazit plný text záznamu Full Text from ScienceDirect