Synthesis Of Tetracoordinate 1,2-Oxaselenetanes And Their Oxirane Formation Reaction

Autor:	Takayuki Kawashima, Fumihiko Ohno, Renji Okazaki
Rok vydání:	1998
Předmět:	Oxidative cyclization Tetracoordinate Ligand Reaction formation Chemistry Organic Chemistry Thermal decomposition Biochemistry Medicinal chemistry law.invention Inorganic Chemistry law Yield (chemistry) Walden inversion
Zdroj:	Phosphorus, Sulfur, and Silicon and the Related Elements. 136:501-504
ISSN:	1563-5325 1042-6507
DOI:	10.1080/10426509808545982
Popis:	Tetracoordinate trans- and cis-3,4-diphenyl-4-trifluoromethyl-1,2-oxaselenetanes bearing the Martin ligand were synthesized by the oxidative cyclization of the corresponding β-hydroxyalkyl selenides with Br2 in the presence of Et3N. Their thermolysis afforded the corresponding oxiranes stereospecifically in a high yield with retention of configuration, though a small amount (2%) of an inverted product was obtained from the trans-isomer.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::27dd319040cae7da4f2a54bcdacf61f8 https://doi.org/10.1080/10426509808545982 Zobrazit plný text záznamu