Kinetics and Mechanistic Approach to the Benzimidazolium fluorochromate Oxidation of Indole-2-aldehyde in various percentages of Acetic acid and Water mixture

Autor:	I. Vannamuthu, V. Saleem Malik, S. Sheik Mansoor, S. Syed Shafi
Rok vydání:	2015
Předmět:	chemistry.chemical_classification Indole test Green chemistry General Chemistry Radiation chemistry Biochemistry Aldehyde Medicinal chemistry Catalysis Solvent Acetic acid chemistry.chemical_compound chemistry Drug Discovery Environmental Chemistry Perchloric acid
Zdroj:	Oriental Journal of Chemistry. 31:77-83
ISSN:	2231-5039 0970-020X
Popis:	The kinetics of benzimidazolium fluorochromate (BIFC) catalysed oxidation of indole-2aldehyde (2-InA) with perchloric acid in 50% acetic acid–50% water solvent mixture at 303 K has been followed spectrophotometrically. The reaction is first order with respect to [BIFC], [2-InA] and [H + ] and the reaction is catalyzed by hydrogen ions. A suitable mechanism has been proposed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::27d4383393c87464d744d112d16bfe31 https://doi.org/10.13005/ojc/310108 Zobrazit plný text záznamu