Inhibition of Copper Corrosion with N-Arylaminotriazoles in Aqueous Chloride Solutions and in Air
| Autor: | D.S. Shevtsov, I.D. Zartsyn, Oleg A. Kozaderov, Ekaterina Komarova, Anuj Tripathi, Ch. Prabhakar, A. Yu. Potapov, A.A. Kruzhilin, G. O. Kipriyanova, Kh. S. Shikhaliev |
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| Rok vydání: | 2020 |
| Předmět: |
chemistry.chemical_classification
Aqueous solution General Chemical Engineering Salt (chemistry) chemistry.chemical_element 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Electrochemistry 01 natural sciences Chloride Copper 0104 chemical sciences Corrosion chemistry medicine Erosion corrosion of copper water tubes 0210 nano-technology medicine.drug Nuclear chemistry |
| Zdroj: | Russian Journal of Applied Chemistry. 93:1152-1159 |
| ISSN: | 1608-3296 1070-4272 |
| DOI: | 10.1134/s1070427220080078 |
| Popis: | A series of 3-(N-arylamino)-5-amino-1Н-1,2,4-triazoles were prepared by the reaction of S,S-dimethyl cyanodithioimidocarbamate with appropriate anilines. The inhibiting effect of the products on the corrosion of copper of M1 grade in acidic and neutral chloride-containing media was studied using electrochemical and accelerated electroless methods. The maximal degree of protection ensured by commercially available 3,5-diamino-1H-1,2,4-triazole and the synthesized 3-phenylamino, 3-(4-methylphenylamino), 3-(4-chlorophenylamino), and 3-(3-chlorophenylamino) derivatives of 5-amino-1Н-1,2,4-triazole reaches 70–87%. In acid solutions, the synthesized compounds show higher performance than the 3,5-diamino derivative, ensuring up to 92–96% protection. Similar results were obtained in experiments in a salt fog chamber. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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