Spectroscopic study of (nitroalkyl)nitrosamines

Autor:	R. G. Gafurov, L. T. Eremenko, E. M. Sogomonyan, T. I. Kedrova
Rok vydání:	1979
Předmět:	Electronegativity chemistry.chemical_compound chemistry Nitrosamine Absorption band Bathochromic shift Substituent Infrared spectroscopy General Chemistry Nitroso Physics::Chemical Physics Bond energy Photochemistry
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 28:944-947
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00963302
Popis:	1. A study has been made of the electronic and vibrational spectra of (nitroalkyl)nitrosamines. It has been shown that an increase in the substituent electronegativity leads to a bathochromic shift in the long-wave maximum. The nitrosamine absorption band has been identified by the isotopic substitution method. 2. The frequencies of the nitroso group stretching vibrations in the IR spectrum, and the short-wave absorption band in the UV spectra, have been correlated with N-N bond energies. 3. Frequencies and normal vibration forms for the nitrosamine group have been calculated.
Databáze:	OpenAIRE
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