Dihydrobis- and tris(triphenylphosphine)rhodium(III) carboxylate complexes

Autor:	Marie-Paula Belciug, Gary Pattrick, Laurence Carlton
Rok vydání:	1992
Předmět:	Tris chemistry.chemical_element Medicinal chemistry Rhodium Inorganic Chemistry chemistry.chemical_compound chemistry Yield (chemistry) Pyridine Materials Chemistry Organic chemistry Carboxylate Physical and Theoretical Chemistry Triphenylphosphine
Zdroj:	Polyhedron. 11:1501-1506
ISSN:	0277-5387
DOI:	10.1016/s0277-5387(00)83143-5
Popis:	The complexes [Rh(H)2(O2CArN)(PPh3)2] (O2CArN = pyridine-2-carboxylate, 6-methylpyridine-2-carboxylate, pyrazine-2-carboxylate, quinoline-2-carboxylate, isoquinoline-1-carboxylate and quinoxaline-2-carboxylate) were formed in high yield by the reaction of [RhH(PPh3)4] with the carboxylic acids NArCO2H; their properties are compared with those of [Rh(H)2(O2CR)(PPh3)3] and [Rh(H)2(O2CR)(PPh3)2(py)] (O2CR = acetate, thiophene-2-carboxylate; py = pyridine).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::27a3b12a3eb94b17800c84058d6b4987 https://doi.org/10.1016/s0277-5387(00)83143-5 Zobrazit plný text záznamu