Preparation and characteristic of high surface area lignin-based porous carbon by potassium tartrate activation

Autor: Zhao Huifang, Bei Liu, Hu Dinggen, Zhongyu Yan, Chen Jianbin, Lizheng Sha, Yuan Kangshuai, Daliang Guo
Rok vydání: 2021
Předmět:
Zdroj: Microporous and Mesoporous Materials. 326:111340
ISSN: 1387-1811
DOI: 10.1016/j.micromeso.2021.111340
Popis: In order to study the property of lignin-based porous carbon activated by potassium tartrate, the effects of activator types, activator/lignin mass ratio and activation temperature on the surface morphology, specific surface area and pore size distribution of alkali lignin based porous carbon materials were systematically investigated. Meanwhile, the methyl orange adsorption capacity and adsorption kinetics of the lignin-based porous carbon were also evaluated. The N2 adsorption-desorption experiment results showed that the specific surface area value of lignin-based porous carbon materials activated by potassium tartrate (APC-J), KOH (APC-K), and NaOH (APC-Na) are 947, 1113 and 762 m2/g, respectively. Meanwhile, APC-J has a special microporous structure, while the pore structures of APC-K and APC-Na are mainly mesopores. The best specific surface area of lignin-based porous carbon materials was 1911 m2/g obtaining from APC-J-2-8 sample (mass ratio 2:1, activation temperature 800 °C). The adsorption experiment of methyl orange (MO) showed that the adsorption kinetics of APC-J-2-8 conformed to the quasi-second-order kinetic model, mainly chemical adsorption. The isothermal adsorption process conforms to the Langmuir adsorption isothermal adsorption model, which is a single molecular layer adsorption, and the maximum adsorption amounts are 526.31 mg/g.
Databáze: OpenAIRE
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