| Autor: |
Andreas Boelke, Thomas J. Kuczmera, Boris J. Nachtsheim, Enno Lork |
| Rok vydání: |
2021 |
| Předmět: |
|
| DOI: |
10.26434/chemrxiv.14567472.v1 |
| Popis: |
Herein we describe the first systematic investigation of cyclic iodonium salts (iodoliums and iodazoliums) and their performance as XB-donors in a variety of benchmark reactions. It was found that further N-alklyation of the N-heterocycle has a significant influence on their XB-donor capability. These novel dicationic species show a reactivity which is comparable or even better than the best so far described iodine(I) and iodine(III) compounds throughout the investigated reaction set. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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