Measurements and correlation of high-pressure VLE of binary CO2–alcohol systems (methanol, ethanol, 2-methoxyethanol and 2-ethoxyethanol)

Autor:	Chul Lee, Seung Nam Joung, Wan Soo Huh, Ki-Pung Yoo, Hun Yong Shin, Chang Woo Yoo, Sun Young Kim
Rok vydání:	2001
Předmět:	2-Methoxyethanol Equation of state Ethanol General Chemical Engineering General Physics and Astronomy Thermodynamics Alcohol Primary alcohol chemistry.chemical_compound 2-Ethoxyethanol chemistry Methanol Binary system Physical and Theoretical Chemistry
Zdroj:	Fluid Phase Equilibria. 185:219-230
ISSN:	0378-3812
DOI:	10.1016/s0378-3812(01)00472-1
Popis:	High-pressure vapor–liquid equilibrium (VLE) data were measured for binary CO 2 –alcohol systems (e.g. methanol, ethanol, 2-methoxyethanol, and 2-ethoxyethanol) at various isotherms (313.15–345.15 K). The quantitative VLE data and mixture critical conditions were measured using a new design for a circulation VLE system. The measure data were correlated by the classical Peng–Robinson and the multi-fluid nonrandom lattice fluid hydrogen-bonding (MF-NLF-HB) equation of state. The MF-NLF-HB model was formulated previously by the present authors based on the proton donor–acceptor principle to the hydrogen-bonding interaction in CO 2 –alcohol systems. For the measured and calculated data of CO 2 –alcohol systems, the relative accuracy of the data was discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::277207c5888a6573fd281b17a2a04de9 https://doi.org/10.1016/s0378-3812(01)00472-1 Zobrazit plný text záznamu Full Text from ScienceDirect