Detection of uncombined oxygen in zirconium metal

Autor:	Louis Silverman, Wanda Bradshaw
Rok vydání:	1958
Předmět:	Zirconium Inorganic chemistry chemistry.chemical_element Iodine Biochemistry Oxygen Chemical reaction Analytical Chemistry Metal chemistry.chemical_compound Hydrofluoric acid chemistry visual_art Zirconium oxide visual_art.visual_art_medium Environmental Chemistry Molecular oxygen Spectroscopy
Zdroj:	Analytica Chimica Acta. 18:253-258
ISSN:	0003-2670
DOI:	10.1016/s0003-2670(00)87136-6
Popis:	This study was undertaken to develop a means of determining oxygen in zirconium which is present in a form other than that of zirconium oxide. The method described determines oxygen which is evolved as molecular oxygen when solid zirconium metal is dissolved in hydrofluoric acid solution. The oxygen evolved is caught in a separate flask and ultimately determined colorimetrically as iodine. In this procedure, the oxygen held as ZrO/sub 2/ is not evolved and is not determined. Thc range of oxygen determined by this method was between 50 to 170 mu g which is equivalent to 0.06 to 0.22% oxygen. The deviation was plus or minus 0.01% oxygen. (auth)
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::276bc5aa2aae2374ead023601aa6ae45 https://doi.org/10.1016/s0003-2670(00)87136-6 Zobrazit plný text záznamu