CuO supported 1-methyl-3-(3-(trimethoxysilyl) propyl) imidazolium chloride (MTMSP-Im/Cl) nanoparticles as an efficient simple heterogeneous catalysts for synthesis of β-azido alcohols

Autor: Rashid Badri, E. Fadavipoor, Haleh Sanaeishoar, Ali Reza Kiasat
Rok vydání: 2019
Předmět:
Zdroj: Journal of the Iranian Chemical Society. 16:1451-1458
ISSN: 1735-2428
1735-207X
DOI: 10.1007/s13738-019-01623-4
Popis: In the present study, CuO supported 1-methyl-3-(3-(trimethoxysilyl) propyl) imidazolium chloride (MTMSP-Im/Cl) is synthesized as a novel, efficient and eco-friendly heterogeneous nanocatalyst. This nanocatalyst was applied for selective ring opening of epoxides with azide anion in water. Structure and morphology of the obtained catalyst were investigated by FT-IR spectroscopy, XRD, TGA, FE-SEM, and EDX techniques. All the results confirmed that MTMSP-Im/Cl is grafted on to CuO nanoparticles. The synthesized nanohybrid can be easily separated after completion of the reaction and reused for four cycles without any significant reduction of its catalytic activity.
Databáze: OpenAIRE