CuO supported 1-methyl-3-(3-(trimethoxysilyl) propyl) imidazolium chloride (MTMSP-Im/Cl) nanoparticles as an efficient simple heterogeneous catalysts for synthesis of β-azido alcohols
Autor: | Rashid Badri, E. Fadavipoor, Haleh Sanaeishoar, Ali Reza Kiasat |
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Rok vydání: | 2019 |
Předmět: | |
Zdroj: | Journal of the Iranian Chemical Society. 16:1451-1458 |
ISSN: | 1735-2428 1735-207X |
DOI: | 10.1007/s13738-019-01623-4 |
Popis: | In the present study, CuO supported 1-methyl-3-(3-(trimethoxysilyl) propyl) imidazolium chloride (MTMSP-Im/Cl) is synthesized as a novel, efficient and eco-friendly heterogeneous nanocatalyst. This nanocatalyst was applied for selective ring opening of epoxides with azide anion in water. Structure and morphology of the obtained catalyst were investigated by FT-IR spectroscopy, XRD, TGA, FE-SEM, and EDX techniques. All the results confirmed that MTMSP-Im/Cl is grafted on to CuO nanoparticles. The synthesized nanohybrid can be easily separated after completion of the reaction and reused for four cycles without any significant reduction of its catalytic activity. |
Databáze: | OpenAIRE |
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