New pentafluorophenyliodine(III) and (V) compounds
| Autor: | H.J. Frohn, A. Priwitzer, S. Görg |
|---|---|
| Rok vydání: | 1992 |
| Předmět: |
Substitution reaction
Aryl Organic Chemistry Synthon chemistry.chemical_element Biochemistry Inorganic Chemistry chemistry.chemical_compound Electrophilic substitution chemistry Electrophile Fluorine Environmental Chemistry Organic chemistry Reactivity (chemistry) Lewis acids and bases Physical and Theoretical Chemistry |
| Zdroj: | Journal of Fluorine Chemistry. 58:320 |
| ISSN: | 0022-1139 |
| DOI: | 10.1016/s0022-1139(00)80782-4 |
| Popis: | The synthesis of (C6F5)2IF and (C6F5)3I was achieved by using C6F5IF2 as a synthon in fluorine aryl substitution. The new compounds which are stable at room temperature were analytically and spectroscopically characterized. Initial findings of their reactivity will be discussed. C6F5I(O)F2-synthesized by fluorine-oxo substitution on C6F5IF4-reacts with Lewis acids forming the electrophilic species [C6F5I(O)F]+. Among other reactions, electrophilic substitution reactions on aromatic compounds will be reported in detail. New results of fluorine aryl polysubstitution reactions on C6F5I(O)F2 and C6F5IF4 will be also presented. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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