The synthesis of feldspars at temperatures between 0 �?80 � C, their ordering behaviour and twinning

Autor: Werner Flehmig
Rok vydání: 1977
Předmět:
Zdroj: Contributions to Mineralogy and Petrology. 65:1-9
ISSN: 1432-0967
0010-7999
DOI: 10.1007/bf00373564
Popis: Potassium feldspars, albites, plagioclases (20–38% An) and quartz were synthesized at very low temperatures by means of hydroxide gels in aqueous solutions which may be similar to the solute contents in natural environments. The formation of plagioclases in this connection is likely to be metastable. Optical and X-ray examinations of single feldspar crystals revealed the presence of monoclinic and triclinic potassium feldspars, intermediate albite, and low albite with high chemical purity in each case. Degree of ordering and chemical composition of the resulting feldspars depends on pH and alkali concentration. Higher pH and salt concentrations produced more and more ordered feldspars. In the experiments the formation of albite was restricted to pH values above 8, whereas the growth of potassium feldspars has taken place in a greater pH range between 5–10. A characteristic feature of gel grown feldspars are the nearly non-idiomorphic shapes of larger crystals and the occurrence of polysynthetic twinning probably indicating rapid crystallization after nucleation.
Databáze: OpenAIRE