Synthesis, structure, and magnetic properties of the novel sodium cobalt tellurate Na5Co15.5Te6O36
| Autor: | Yue Jin Shan, Keitaro Tezuka, Hideo Imoto, Makoto Wakeshima, Yuta Yoshioka |
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| Rok vydání: | 2014 |
| Předmět: |
Materials science
Space group Condensed Matter Physics Magnetic susceptibility Tellurate Electronic Optical and Magnetic Materials Inorganic Chemistry Crystallography Magnetization chemistry.chemical_compound Ferromagnetism chemistry Materials Chemistry Ceramics and Composites Antiferromagnetism Physical and Theoretical Chemistry Single crystal Néel temperature |
| Zdroj: | Journal of Solid State Chemistry. 211:63-68 |
| ISSN: | 0022-4596 |
| DOI: | 10.1016/j.jssc.2013.12.003 |
| Popis: | The novel single crystal oxide Na5Co15.5Te6O36 had been successfully synthesized by a self-flux method. Na5Co15.5Te6O36 crystallizes in hexagonal symmetry, space group P63/m (No.176), with lattice parameters a=9.359 (3) A, c=9.096 (8) A, and Z=1. The structure is composed of combining the edge-sharing chains of octahedra, [TeO6]6− and [Co(1)O6]10− with the face-sharing chains of triangular prisms, [Co(2)O6]10− and [Co(3)(Na(3))O6]10−. Sodium ions partially occupy hexagonal channels along the c-axis that are formed by the connection of the chains. The magnetic susceptibility data show a long-range antiferromagnetic ordering with a Neel temperature of 52 K along the c axis. At temperatures above 200 K, the susceptibility corrected for the diamagnetic contribution can be fit to the Curie–Weiss law for Co2+ (S=3/2). The anisotropic ferromagnetic and antiferromagnetic feature of Na5Co15.5Te6O36 was obtained through field-dependent magnetization measurements at low temperature. The ferromagnetic and antiferromagnetic behaviors can be considered from the interactions between the Co ions in 1D zig-zag chains formed by sharing the edges of the Co(1)O6 octahedra, and the interactions between the interchain Co ions, respectively. |
| Databáze: | OpenAIRE |
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