Unprecedented Elimination of Conjugated Phenylthioether Groups by Low-Valent Titanocene

Autor:	Stephane Streiff, Laurent Désaubry, Nigel Ribeiro, Ludivine Fetzer
Rok vydání:	2010
Předmět:	Elimination reaction chemistry.chemical_compound Thioether chemistry Organic Chemistry Combinatorial chemistry
Zdroj:	Synlett. 2010:2928-2930
ISSN:	1437-2096 0936-5214
DOI:	10.1055/s-0030-1259009
Popis:	The first thioether elimination reaction utilizing a low-valent titanocene has been discovered. This reaction occurs under mild conditions and affords stereospecifically a variety of dienes and styrenes. Our data suggest that this new reaction involves an intermediate of dimerization of titanocene as the reactant responsible for this elimination.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::271db09092f708c0274d4a52a1681811 https://doi.org/10.1055/s-0030-1259009 Zobrazit plný text záznamu