Photoproduction of homogeneous chromium(V) compounds in pentanol for targets containing polarized hydrogen nuclei

Autor:	É. I. Bunyatova, V. P. Sherstyuk, S. M. Maloletov
Rok vydání:	1991
Předmět:	Hydrogen Spectrometer Analytical chemistry chemistry.chemical_element General Chemistry Laser Ammonium dichromate law.invention chemistry.chemical_compound Paramagnetism Chromium chemistry law Ammonium Spectroscopy
Zdroj:	Theoretical and Experimental Chemistry. 27:57-60
ISSN:	1573-935X 0040-5760
DOI:	10.1007/bf01372925
Popis:	Measurements have been made on photochemical and subsequent dark reactions with an He-Cd laser (44l nm) with ammonium dichromate solutions in pentanol. Exposing the solution directly in the spectrometer cavity leads to an ESR signal having g = 1.973 characteristic of chromium(V) compounds. The compounds have been examined by ESR and optical spectroscopy. A kinetic analysis is presented. It is suggested that homogeneous Cr(V) compounds are formed. No Cr(III) or other paramagnetic products have been detected. These compounds can be used in polarized nuclear targets.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::27126f14c2c73469fc5ce79f3c60de9c https://doi.org/10.1007/bf01372925 Zobrazit plný text záznamu Full text from SpringerLink