Raman Study of Hydrogenated and Fluorinated Single‐walled Carbon Nanotubes

Autor: Dimitris Christofilos, G. A. Kourouklis, K. P. Meletov, V. A. Davydov, Valery N. Khabashesku, I. O. Bashkin, J. Arvanitidis, Merlyn X. Pulikkathara, V. V. Shestakov, A. V. Krestinin
Rok vydání: 2008
Předmět:
Zdroj: Fullerenes, Nanotubes and Carbon Nanostructures. 16:322-329
ISSN: 1536-4046
1536-383X
Popis: Hydrogenated and fluorinated single‐walled carbon nanotubes (SWNT‐H and SWNT‐F) were investigated by micro‐Raman spectroscopy. The as‐prepared SWNT‐H exhibits giant structureless hot luminescence that screens the Raman peaks. The luminescence background, attributed to random binding of the hydrogen atoms, gradually decreases upon annealing of the sample. In contrast, the as‐prepared SWNT‐F shows no luminescence but the Raman peaks are rather broad. The annealing of SWNT‐F results in structural ordering due to fluorine removal.
Databáze: OpenAIRE