Fluorine-containing polymers. VI. Copolymerization of 1,1-dihydroperfluorobutyl acrylate

Autor:	C. L. Sandberg, F. A. Bovey
Rok vydání:	1955
Předmět:	chemistry.chemical_compound Acrylate Monomer chemistry Polymer chemistry Substituent Copolymer Methyl methacrylate Acrylonitrile Methyl acrylate Styrene
Zdroj:	Journal of Polymer Science. 15:553-557
ISSN:	1542-6238 0022-3832
DOI:	10.1002/pol.1955.120158022
Popis:	A study of the copolymerization of 1,1-dihydroperfluorobutyl acrylate with methyl methacrylate, styrene, and butadiene has shown that this monomer is similar to acrylonitrile (e = 1.2, Q = 0.44) in its copolymerization behavior and considerably different from methyl acrylate (e = 0.6, Q = 0.42). This illustrates the strongly electronegative character of the C3F7 group. The higher Q value (0.75) may be considered evidence of higher resonance stability of the radical adduct due to the perfluoroalkyl substituent.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::27031951062ea4e946efcf61c7d4232a https://doi.org/10.1002/pol.1955.120158022 Zobrazit plný text záznamu Plný text