| Autor: |
Usein M. Dzhemilev, Yu. G. Budnikova, Zulfiya R. Shakirova, Airat R. Tuktarov, R. B. Salikhov |
| Rok vydání: |
2016 |
| Předmět: |
|
| Zdroj: |
ChemInform. 47 |
| ISSN: |
0931-7597 |
| DOI: |
10.1002/chin.201644093 |
| Popis: |
The reaction of fullerene C60 with isocyanoacetates and EtMgBr in the presence of stoichiometric amounts of Ti(Oi-Pr)4 was studied for the first time. Unlike esters and nitriles of carboxylic acids and isonitriles, isocyanoacetates were found to react with C60 under the developed conditions to give N-unsubstituted pyrrolidinofullerenes. The electrochemical reduction of the C60 derivatives we synthesized was found to proceed less easily than that of C60 but more easily than that of unsubstituted pyrrolidinofullerenes. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
|
Plný text