NEW SYMMETRIC DIISOPROPYLPHOSPHORYL-S-ALKANEDI YLDIISOTHIOUREAS. INVESTIGATIONS ON THEIR SYNTHESIS

Autor:	Denise R. Araripe, Aniy K. Ohara, Janaina C. Kuwata, Marcos C. de Souza, Patricia Camacho Dias
Rok vydání:	1999
Předmět:	Inorganic Chemistry Carbon chain chemistry.chemical_compound chemistry Stereochemistry Organic Chemistry Biochemistry Phosphonate Isopropyl
Zdroj:	Phosphorus, Sulfur, and Silicon and the Related Elements. 148:143-148
ISSN:	1563-5325 1042-6507
Popis:	Symmetric dialkylphosphoryl-S-alkanediyldiisothiouas (RO)2P(O)NHC(=NH)S(CH2)n SC(=NH)NHP(O)(OR)2 (I, R = isopropyl; n = 2–5) have potential coordination sites involving O, P, N and S as donors atoms. For their synthesis, common two-phase reactions between the corresponding diisothiourea derivatives and diisopropyi phosphonate were unsuccessful. Herein we describe a new synthesis for such compounds using diisopropyl chlorophosphonate. Two new bis-phosphorylated alkanediyldiisothioureas with increasing carbon chain (I; n = 3, n = 5) were prepared by this method.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::26f3baebd8a052ab8d632fd3a9fffe2a https://doi.org/10.1080/10426509908037006 Zobrazit plný text záznamu