Autor:	G.I. Panov, K.A. Dubkov, Larisa V. Pirutko, E.V. Starokon
Rok vydání:	2003
Předmět:	inorganic chemicals Inert Reducing agent Inorganic chemistry chemistry.chemical_element Charge (physics) General Chemistry Photochemistry Oxygen Catalysis Ion chemistry Mössbauer spectroscopy
Zdroj:	Topics in Catalysis. 23:137-143
ISSN:	1022-5528
DOI:	10.1023/a:1024832606400
Popis:	According to previous Mossbauer data [1] α-sites formation at the activation of Fe-containing zeolites is accompanied by irreversible “self-reduction” of the iron, proceeding without participation of an external reducing agent. Reduced Fe2+ ions are inert to O2 but are reversibly oxidized to Fe3+ by N2O, generating the α-oxygen species, Oα, which provide selective oxidation of hydrocarbons.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::26db9a46490377e6fcdd4a86f9f6f88f https://doi.org/10.1023/a:1024832606400 Zobrazit plný text záznamu Full text from SpringerLink