Kinetics and mechanism of thermolysis of 1-phenyl-2-pyridylethanes

Autor:	Igor V. Kalechitz, E.N. Grigorieva, V. Yu. Korobkov, V. I. Bykov
Rok vydání:	1995
Předmět:	Reaction mechanism Chemistry General Chemical Engineering Thermal decomposition Heteroatom Kinetics Inorganic chemistry Energy Engineering and Power Technology chemistry.chemical_element Nitrogen Meta Fuel Technology Reaction rate constant Physical chemistry Pyrolysis
Zdroj:	Fuel Processing Technology. 43:183-189
ISSN:	0378-3820
DOI:	10.1016/0378-3820(95)00007-t
Popis:	Kinetics and mechanism of thermolysis of 1-phenyl-2-(4-pyridyl)ethane have been studied and the thermolysis rate constants of its two isomers have been calculated. The calculated and experimentally determined thermolysis rate constants of 1-phenyl-2-(3-pyridyl)ethane agree well. Compared with 1,2-diphenylethane, the introduction of heteroatom, nitrogen into meta position accelerated the thermolysis slightly, but retarded it into para- and ortho-position.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::26c86a52e4836473ceb926f57907aadb https://doi.org/10.1016/0378-3820(95)00007-t Zobrazit plný text záznamu Full Text from ScienceDirect