| Autor: |
Dah‐YuKao, Jenn-Shing Chen, Chi‐Chyuang Lin, Juh‐Ann Lin, Wei‐Chen Luo |
| Rok vydání: |
2000 |
| Předmět: |
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| Zdroj: |
Journal of the Chinese Chemical Society. 47:1177-1183 |
| ISSN: |
0009-4536 |
| DOI: |
10.1002/jccs.200000159 |
| Popis: |
This work in ves ti gated not only the equi lib rium of self-association of 2-pyrrolidone (A) and that of 2-hydroxyl-4-methyl-pyridine (B), but also the het ero-association be tween A and B in [ 2 H 3]acetonitrile through hy dro gen bond ing us ing high-resolution nu clear mag netic res o nance spec tros copy. Di lu tion shift data for the pro tons of the NH group of A and OH group of B were mea sured over a wide range of tem per a tures and con cen tra tions. In ad di tion, the mono mer shifts, dimer shifts and dimerization con stants of self-association and het ero-association were eval u ated us ing a graphic method op er at ing on the di lu tion chem i cal shift data. The enthalpy and en tropy of dimerization of self-association and het ero-association were also ob tained from the van’t Hoff plot. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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