Synthesis of Rh III Anilido, Hydroxide, and Methoxide Complexes

Autor:	Samantha A. Burgess, Michal Sabat, T. Brent Gunnoe, Tamara Bolaño, William H. Myers
Rok vydání:	2015
Předmět:	Inorganic Chemistry chemistry.chemical_compound chemistry 19f nmr spectroscopy Octahedron Inorganic chemistry chemistry.chemical_element Hydroxide Nuclear magnetic resonance spectroscopy Methoxide Trifluoromethanesulfonate Medicinal chemistry Rhodium
Zdroj:	European Journal of Inorganic Chemistry. 2015:1041-1052
ISSN:	1099-0682 1434-1948
DOI:	10.1002/ejic.201403147
Popis:	The octahedral RhIII complexes [(tbpy)2Rh(XH)2][OTf]3 (tbpy = 4,4′-di-tert-butyl-2,2′-bipyridyl; X = NHPh or OH; OTf = trifluoromethanesulfonate), [(tbpy)2Rh(X)2][OTf] (X = NHPh or OH), [(tbpy)2Rh(NHPh)(NH2Ph)][OTf]2, [(tbpy)2Rh(Me)(NH2Ph)][OTf][BAr′4] (BAr′4 = tetrakis[(3,5-bis-trifluoromethyl)phenyl]borate), [(tbpy)2Rh(Me)(NHPh)][BAr′4], [(tbpy)2Rh(OMe)(Cl)]Cl, and [(bpy)Rh(X)2][PF6] (bpy = 2,2′-bipyridyl; X = OH, OMe) have been synthesized and characterized by 1H, 13C{1H}, and 19F NMR spectroscopy, elemental analysis, or high-resolution mass spectrometry as well as single-crystal X-ray diffraction for some complexes. A comparison of the solid-state structural data for [(tbpy)2Rh(Me)(NH2Ph)]2+, [(tbpy)2Rh(NH2Ph)2]3+, [(tbpy)2Rh(NHPh)2]+, and [(tbpy)2Rh(NHPh)(NH2Ph)]2+ is included.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::264d9fdfa371bf6f33c1f5e2645a2fa4 https://doi.org/10.1002/ejic.201403147 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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