Strategies for Pore Engineering in Zirconium Metal-Organic Frameworks
| Autor: | Hong-Cai Zhou, Shuai Yuan, Liang Feng, Kun-Yu Wang, Gregory S. Day |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
Chemical process
Zirconium Materials science General Chemical Engineering Biochemistry (medical) chemistry.chemical_element Nanotechnology 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Biochemistry 0104 chemical sciences chemistry Materials Chemistry Environmental Chemistry Surface modification Metal-organic framework Cooperative behavior 0210 nano-technology Porous medium Porosity |
| Zdroj: | Chem. 6:2902-2923 |
| ISSN: | 2451-9294 |
| Popis: | Summary Pore engineering is the design and synthesis of porous structures with desired pore environments and properties. It includes, but is not limited to, pore construction, functionalization, combination, and partitioning. This review explores current strategies utilized to engineer pores in zirconium metal-organic frameworks (Zr-MOFs). Zr-MOFs are viewed as one of the most promising MOF materials for practical applications because of their diverse topologies, excellent stability, unique properties, and versatile functions. The structural modification of the intrinsic cavities within Zr-MOFs results in alteration of functionality, such as selective recognition and cooperative behavior. This structure-property relationship highlights the importance of constructing pore spaces with precisely controlled sizes and functionalities for various chemical processes. Altogether, we aim to offer fresh insights into the design of porous materials with enhanced structural complexity and functionality, which will expand the synthetic toolkit for the future development of increasingly complex functional MOFs with tailored pore environments. |
| Databáze: | OpenAIRE |
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