Incorporation of Cu into Li[Ni1/3Co1/3Mn1/3]O2 cathode: Elucidating its electrochemical properties and stability
| Autor: | Kyungjung Kwon, Sanghyuk Park, Minsang Jo, Jun Ho Song |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Materials science
Mechanical Engineering Metals and Alloys 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Electrochemistry 01 natural sciences Cathode 0104 chemical sciences law.invention Anode Ion Metal Chemical engineering Mechanics of Materials law Impurity visual_art Materials Chemistry visual_art.visual_art_medium Graphite Leaching (metallurgy) 0210 nano-technology |
| Zdroj: | Journal of Alloys and Compounds. 764:112-121 |
| ISSN: | 0925-8388 |
| DOI: | 10.1016/j.jallcom.2018.06.015 |
| Popis: | Resynthesized cathode active materials from the leaching solution of spent lithium ion batteries can contain a Cu impurity element, which is anode current collector. There is also a lack of consensus on the effects of Cu doping element/impurity in cathode active materials. We synthesize LiNi1/3Mn1/3Co1/3O2 (NCM) active materials with the addition of Cu. The effects of Cu on the electrochemical properties (initial charge/discharge capacity, rate capability, and cycleability) of NCM cathode are investigated under different experimental conditions such as cutoff voltage and temperature. Initial charge/discharge capacities gradually decrease and rate capability deteriorates with increasing the Cu content. The enhanced capacity retention of NCM with a certain range (∼1.5 mol%) of Cu content is obtained. A decline in the discharge capacity of the full cell, where graphite is adopted as anode active material, is more prominent than that of the half cell. Whereas the graphite anode before cycling contains no metal component on the surface, the surface composition on the graphite anode after cycling is dominated mostly by Cu, followed by Mn, with a negligible amount of Co and Ni. Cu in the NCM cathode dissolves and the dissolved Cu ions are deposited on the graphite surface, which would deteriorate the full cell performance. |
| Databáze: | OpenAIRE |
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