Chemical modification of the polymeric sorbent containing hydroxyl functional groups

Autor:	Barbara Gawdzik, J. Osypiuk, Tadeusz Matynia
Rok vydání:	1997
Předmět:	Chemistry Organic Chemistry Clinical Biochemistry Dimethyldichlorosilane Chemical modification Biochemistry Chloride Analytical Chemistry chemistry.chemical_compound Homologous series Acyl chloride Polymer chemistry medicine Copolymer Organic chemistry Stearic acid Selectivity medicine.drug
Zdroj:	Chromatographia. 44:25-30
ISSN:	1612-1112 0009-5893
DOI:	10.1007/bf02466511
Popis:	Dimethyldichlorosilane and stearic acid chloride were used for deactivation of hydroxyl functional groups present in the skeleton of the methacrylic ester ofp,p′-dihydroxydiphenylpropane diglycidyl ether-divinylbenzene, porous copolymer used as HPLC packing. The influence of chemical modification on the chromatographic behaviour of the copolymer was studied. To characterize selectivity of the packings, retention indices of five homologous series and test compounds were determined. The data obtained suggest that modification with stearic acid chloride affects both the chemical and porous structure of the copolymer while modification with dimethydichlorosilane changes only the chemical character of the packing.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::25d91389f974e1f1f37e5df006e545d2 https://doi.org/10.1007/bf02466511 Zobrazit plný text záznamu Full text from SpringerLink