Synthesis of bicyclo[2.2.1]heptyl oxyalkanes and acrylates based on them

Autor:	M. K. Mamedov, G. N. Mekhtieva, Kh. G. Gurbanova
Rok vydání:	2014
Předmět:	chemistry.chemical_compound Acrylate Addition reaction Monomer chemistry Bicyclic molecule General Chemical Engineering Yield (chemistry) Diol Polymer chemistry General Chemistry Catalysis Acrylic acid
Zdroj:	Russian Journal of Applied Chemistry. 87:1446-1449
ISSN:	1608-3296 1070-4272
Popis:	Addition reactions of ethane-1,2-diol, propane-1,3-diol, and butane-1,4-diol to bicyclo[2,2,1]hept-2-ene in the presence of a catalyst BF3 OEt2 were studied for deriving reactive monomer, therewith bicyclo[2.2.1] hept-2-oxyalcanols with a yield of 91.2–96.0% were synthesized. In the second stage esterification of the obtained bicyclo[2.2.1]hept-2-oxyalkanols was conducted with acrylic acid in the presence of a catalyst of KU-2-8 H grade and acrylates was also derived with a yield of 87.5–93.0%, which are reactive monomers for synthesis of polymeric glassy products.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::25d8078cf910c97384ce94f318c21b74 https://doi.org/10.1134/s1070427214100097 Zobrazit plný text záznamu Full text from SpringerLink