Regio- and enantioselectivity of Pseudomonas cepacia lipase in the transesterification of 2-substituted-1,4-butanediols

Autor:	Patrizia Ferraboschi, Ada Manzocchi, Enzo Santaniello, Paride Grisenti
Rok vydání:	1994
Předmět:	biology Organic Chemistry Triacylglycerol lipase Regioselectivity Epoxide Transesterification Catalysis Inorganic Chemistry chemistry.chemical_compound chemistry biology.protein Vinyl acetate Organic chemistry Physical and Theoretical Chemistry Lipase Aliphatic compound
Zdroj:	Tetrahedron: Asymmetry. 5:691-698
ISSN:	0957-4166
Popis:	The transesterification of 2-substituted-1,4-butanediols 1a , 2a and 3a with vinyl acetate catalyzed by the Pseudomonas cepacia lipase in organic solvents affords preferentially the 1-acetate, the highest regioselectivity having been found for the epoxydiol 3a , which is enantioselectively resolved [86% ee for the unreacted (S)-(−)- 3a ].
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::25b58c67b49489c29745f4e84deab520 https://doi.org/10.1016/0957-4166(94)80031-6 Zobrazit plný text záznamu