ChemInform Abstract: Synthesis of the Sesquiterpenoid Trichodiene Using a Free Radical Fragmentation Approach
Autor: | Gordon L. Lange, Lorena Furlan, Mark C MacKinnon |
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Rok vydání: | 2010 |
Předmět: | |
Zdroj: | ChemInform. 29 |
ISSN: | 1522-2667 0931-7597 |
DOI: | 10.1002/chin.199842187 |
Popis: | A highly regio- and stereoselective synthesis of the sesquiterpenoid trichodiene is reported. The approach requires only nine steps starting with a [2+2] photoaddition and employs the free radical fragmentation of an “external” cyclobutane bond in a key step. |
Databáze: | OpenAIRE |
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