ChemInform Abstract: Synthesis of the Sesquiterpenoid Trichodiene Using a Free Radical Fragmentation Approach

Autor: Gordon L. Lange, Lorena Furlan, Mark C MacKinnon
Rok vydání: 2010
Předmět:
Zdroj: ChemInform. 29
ISSN: 1522-2667
0931-7597
DOI: 10.1002/chin.199842187
Popis: A highly regio- and stereoselective synthesis of the sesquiterpenoid trichodiene is reported. The approach requires only nine steps starting with a [2+2] photoaddition and employs the free radical fragmentation of an “external” cyclobutane bond in a key step.
Databáze: OpenAIRE