Assumed Mechanism of Polymeric Deposit Formation in Recycle Propylene Washing Column during Bulk Polymerization

Autor:	Alexey Pestryakov, Alla Trofimova, Edward Mayer, Vasiliy Mashukov
Rok vydání:	2015
Předmět:	Polypropylene Materials science Bulk polymerization General Medicine chemistry.chemical_compound Differential scanning calorimetry Polymerization Chemical engineering Volume (thermodynamics) chemistry Scientific method Forensic engineering Slurry Process control
Zdroj:	Applied Mechanics and Materials. 756:179-186
ISSN:	1662-7482
DOI:	10.4028/www.scientific.net/amm.756.179
Popis:	This study presents the results of polymeric deposit analysis from propylene washing column of «Spheripol» process polymerization unit using such methods as gel-permation chromatography, differential scanning calorimetry (DSC), X-ray phase analysis, IR and NMR13C-spectroscopy and analytical process control methods. For comparison the relative data for larger volume polypropylene grades have been presented as well. Based on the findings and available similar practice in a slurry process an assumed formation mechanism was proposed for the discussion.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::252aa6ac41075b1ec1851fd6cf377389 https://doi.org/10.4028/www.scientific.net/amm.756.179 Zobrazit plný text záznamu