ChemInform Abstract: Fluoride Ion-Mediated Peterson Alkenation of Bis(trimethylsilyl)methylimines: A Novel Synthesis of 2-Aza-1,3-dienes and N-Vinyl-β-lactams

Autor: Jesus M. Aizpurua, J. Dunogues, Jean Paul Picard, Claudio Palomo, Juan Lasarte
Rok vydání: 1989
Předmět:
Zdroj: ChemInform. 20
ISSN: 0931-7597
Popis: The formation of bis(trimethylsily)methylimines and their transformation into aza-1,3-dienes by means of a fluoride-induced catalytic Peterson alkenation is reported; when the procedure was applied to N-[bis(trimethylsilyl)methyl]-azetidin-2-ones, a wide range of N-vinyl derivatives were obtained in high yields.
Databáze: OpenAIRE