The importance of resonance stabilization in the benzylic solvolysis. Substituent effects on the solvolysis of α,α-diisopropylbenzyl chlorides

Autor:	Masaaki Mishima, Hirotaka Nakamura, Takashi Kuwamura, Mizue Fujio, Kazuhide Nakata, Yuho Tsuno, Shinjiro Kobayashi, Yoshihiro Saeki
Rok vydání:	1993
Předmět:	Steric effects chemistry.chemical_compound chemistry Organic Chemistry Drug Discovery Substituent Solvolysis Photochemistry Resonance (chemistry) Biochemistry Medicinal chemistry Isopropyl
Zdroj:	Tetrahedron Letters. 34:8309-8312
ISSN:	0040-4039
Popis:	The substituent effect on the solvolysis of α,α-diisopropylbenzyl chlorides can be described in terms of σ+ value. No significant steric loss of resonance was observed by introducing two bulky isopropyl groups into benzylic reaction center.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::25043a613effc3f18b66edb94904227a https://doi.org/10.1016/s0040-4039(00)61418-1 Zobrazit plný text záznamu