Mechanism of Rate Enhancement Using Organic Acids in Nitroxide-Mediated Living Free-Radical Polymerizations
| Autor: | Richard P. N. Veregin, Michael K. Georges, Lora M. Michalak, Peter G. Odell |
|---|---|
| Rok vydání: | 1996 |
| Předmět: |
chemistry.chemical_classification
Nitroxide mediated radical polymerization Polymers and Plastics Bulk polymerization Radical Camphorsulfonic acid Organic Chemistry Radical polymerization Nitroxyl Sulfonic acid Photochemistry Inorganic Chemistry chemistry.chemical_compound Polymerization chemistry Materials Chemistry Organic chemistry |
| Zdroj: | Macromolecules. 29:4161-4163 |
| ISSN: | 1520-5835 0024-9297 |
| DOI: | 10.1021/ma951779d |
| Popis: | It is shown that the primary rate enhancement mechanism due to organic acids such as camphorsulfonic acid in nitroxide-mediated polymerizations involves the consumption of nitroxide radicals. The lower nitroxide concentration affects the equilibrium between growing and dormant chains, increasing the number of growing chains and hence the polymerization rate |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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