Polyfluorinated aryl azides as photoaffinity labelling reagents; the room temperature CH insertion reactions of singlet pentafluorophenyl nitrene with alkanes

Autor:	M. J. T. Young, Matthew S. Platz
Rok vydání:	1989
Předmět:	Nitrene Aryl Organic Chemistry Photodissociation Photochemistry Biochemistry Adduct chemistry.chemical_compound chemistry Yield (chemistry) Drug Discovery Azide Singlet state Cyclopentane
Zdroj:	Tetrahedron Letters. 30:2199-2202
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)99647-3
Popis:	Photolysis of pentafluorophenyl azide in alkanes releases singlet pentafluorophenylnitrene which inserts into the CH bond of cyclopentane to produce an adduct in 28% yield.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::24c1e7ee9648b1ffc760ae91bc9f2d1d https://doi.org/10.1016/s0040-4039(00)99647-3 Zobrazit plný text záznamu