Optimization of polyacrylonitrile–cysteine resin synthesis and its selective removal of Cu(II) in aqueous solutions
| Autor: | Zai-Zai Tong, Lei Fang, Chen Shen, Chunhua Xiong, Pin-Yi Li, Chang Yang, Min Min |
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| Rok vydání: | 2017 |
| Předmět: |
Chelating resin
021110 strategic defence & security studies Aqueous solution Elution Metal ions in aqueous solution Inorganic chemistry 0211 other engineering and technologies Polyacrylonitrile chemistry.chemical_element 02 engineering and technology General Chemistry 021001 nanoscience & nanotechnology Copper Metal chemistry.chemical_compound Adsorption chemistry visual_art visual_art.visual_art_medium 0210 nano-technology |
| Zdroj: | Chinese Chemical Letters. 28:319-323 |
| ISSN: | 1001-8417 |
| DOI: | 10.1016/j.cclet.2016.08.003 |
| Popis: | Polyacrylonitrile beads (PAN) cysteine (CS) was synthesized from polyacrylonitrile beads (PAN) and cysteine (CS). The content of the functional group and the percentage conversion of the functional group of PAN-CS prepared under the optimum condition using response surface methodology (RSM) for the first attempt were 3.22 mmol/g and 35.78%. The structure was characterized by FT-IR and elemental analysis. The adsorption properties of the resin for Cu(II) were investigated by batch and column experiments. Batch adsorption results suggested that PAN-CS had higher adsorption capability for Cu(II) than other metal ions and maximum saturated adsorption capacity was 184.7 mg/g. The resin and its metal complexes were studied by FT-IR. Furthermore, the resin can be eluted easily using 1 mol/L HCl. PAN-CS can provide a potential application for selective removal of copper from waste solution. |
| Databáze: | OpenAIRE |
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