Stereochemistry and mechanism of the nickel-catalysed hydrocyanation of conjugated dienes

Autor:	Jan-E. Bäckvall, Ove Andell
Rok vydání:	1984
Předmět:	inorganic chemicals Nitrile Stereochemistry Cyanide chemistry.chemical_element Reaction intermediate Conjugated system Catalysis chemistry.chemical_compound Nickel chemistry Hydrocyanation Molecular Medicine Acetonitrile
Zdroj:	J. Chem. Soc., Chem. Commun.. :260-261
ISSN:	0022-4936
DOI:	10.1039/c39840000260
Popis:	Nickel-catalysed addition of deuterium cyanide to cyclohedxa-1,3-diene was shown to occur with cis stereochemistry, indicating that a cis-migration of co-ordinated cyanide takes place in an intermediate π-allylnickel complex.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::24bbb71e55c7dbebe1f0c8f420e3f90a https://doi.org/10.1039/c39840000260 Zobrazit plný text záznamu