Synthesis, Structure, and Thermolysis of Tris(dimethylphenylsilyl)methyl Sulfenyl Chloride
| Autor: | Koh Sugamata, Shigeru Ishii |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
inorganic chemicals
Tris Sulfenyl chloride 010405 organic chemistry Thermal decomposition chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Medicinal chemistry Sulfur 0104 chemical sciences chemistry.chemical_compound chemistry Organic chemistry Reactivity (chemistry) Organosulfur compounds Methyl group |
| Zdroj: | Chemistry Letters. 46:837-839 |
| ISSN: | 1348-0715 0366-7022 |
| DOI: | 10.1246/cl.170188 |
| Popis: | Sulfenyl chlorides, i.e., di-coordinated sulfur(II) chlorides are useful precursors for a variety of organic sulfur compounds. Herein, the synthesis, structure, and reactivity of a sulfenyl chloride that bears a bulky tris(dimethylphenylsilyl)methyl group on the sulfur atom are reported. The thermolysis of this sulfenyl chloride resulted in the generation of the corresponding bissilylthioketone via the 1,2-elimination of chlorodimethylphenylsilane. |
| Databáze: | OpenAIRE |
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