Highly catalyst-dependent cycloisomerisation of an O-tethered enyne derived from nerol

Autor:	Philippe Costes, J.A. Ruiz-García, Ulises Jáuregui-Haza, Philippe Kalck, Martine Urrutigoïty, Odile Dechy-Cabaret, Ariadna Fuente-Hernández
Rok vydání:	2010
Předmět:	Enyne Process Chemistry and Technology chemistry.chemical_element Homogeneous catalysis General Chemistry Medicinal chemistry Catalysis Cyclopropane Rhodium chemistry.chemical_compound chemistry Nerol Organic chemistry Selectivity Platinum
Zdroj:	Catalysis Communications. 12:142-146
ISSN:	1566-7367
DOI:	10.1016/j.catcom.2010.08.019
Popis:	The cycloisomerisation of an O-tethered enyne derived from nerol has been studied using various catalytic systems such as PtCl 2 , AuCl 3 , {[AuCl(PPh 3 )]/AgPF 6 } and [Rh 2 Cl 2 (CO) 4 ]. Whatever the catalyst used, formal Alder-ene 1,4-dienes were obtained as major products along with cyclopropane and 1,3-diene derivatives, indicating the crucial influence of the structure of the enyne substrate on the course of the reaction. Differences in terms of activity and selectivity nevertheless appeared when moving from Rh- or Pt-based catalysts to Au(I)-based catalysts: mechanistic pathways are proposed to explain these observations.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2490d089c74f113d5618a272ca34d653 https://doi.org/10.1016/j.catcom.2010.08.019 Zobrazit plný text záznamu Full Text from ScienceDirect