Oxidation of furans with dimethyldioxirane

Autor:	R. W. Murray, Brian M. Adger, M. Anthony McKervey, Joseph Brennan, Collette Barrett
Rok vydání:	1991
Předmět:	Diketone chemistry.chemical_compound Organic peroxide chemistry Yield (chemistry) Acetone Molecular Medicine Organic chemistry Dimethyldioxirane Aliphatic compound Ring (chemistry) Enone
Zdroj:	Journal of the Chemical Society, Chemical Communications. :1553
ISSN:	0022-4936
DOI:	10.1039/c39910001553
Popis:	Dimethyldioxirane reacts rapidly at room temperature in acetone with a variety of furans, furnishing in high yield products of oxidative ring opening and, with 2-furanmethanol, 2H-pyran-3(6H)-one via subsequent ring closure.
Databáze:	OpenAIRE
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